The Origin of the Anomalous Properties of Water


Water has remarkable physical properties that differ from almost all other liquids. Deviation of these properties from a simple liquid exists already in the ambient temperature regime and then becomes strongly enhanced upon supercooling. In particular the finding that the thermodynamic response and correlation functions appear to diverge towards a singular temperature estimated by power-law fits of about 228 K has led to several hypotheses about the origin of waters anomalous properties. One hypothesis to explain the apparent divergence is that there exists a liquid-liquid transitionwith a liquid-liquid critical point at rather high positive pressures. In this scenario the Widom line, defined as the locus of correlation length maxima in the P-T plane, emanates from the critical point as a continuation of the liquid-liquid transition line into the one-phase region and the divergence in the response functions is towards this line. The challenge is that the temperature Tslies below the homogeneous ice nucleation temperature 232 K, a region of the phase diagram that has been denoted as “no man’s land”, since ice crystallization occurs on much faster time scale compared to the experimentally accessible time scale in a typical laboratory setting.

Here I will present how x-rays from x-ray lasers and synchrotron radiation sources can be used to probe the liquid in the deep supercooled water regime inside no-man’s land. In particular I will discuss if a liquid-liquid transition, Widom line and a critical point exists in deep supercooled water causing fluctuations all the way up to ambient temperature.